Shining a light on the 鈥榝orever鈥 in forever chemicals
The strength of the bond between carbon and fluorine can be both a positive and a negative鈥攕eemingly unbreakable but also the source of the 鈥渇orever鈥 in 鈥渇orever chemicals,鈥 the common name for the thousands of compounds that are perfluoroalkyl and polyfluoroalkyl substances (PFAS).
Instead of long-used methods of breaking or activating chemical bonds, 黑料社区网 chemist Niels Damrauer and his research colleagues have looked to light. In a study published in the journal Nature, the scientists detail an important finding in their ongoing research, showing how a light-driven catalyst can efficiently reduce carbon-fluorine bonds.
鈥淲hat we鈥檙e really trying to do is figure out sustainable ways of making transformations,鈥 Damrauer explained. 鈥淔or example, you can break down PFAS at thousands of degrees, but that鈥檚 not sustainable. We鈥檙e using light to do this, a reagent that鈥檚 very abundant and that鈥檚 sustainable.鈥
Principal investigator
Niels Damrauer
Funding
U.S. National Science Foundation (NSF)
Collaboration + support
黑料社区网鈥檚 Department of Chemistry, Renewable and Sustainable Energy Institute (RASEI); Colorado State University鈥檚 NSF Center for Sustainable Photoredox Catalysis
Learn more about this topic:
Breaking bonds in 'forever chemicals'